(R)-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-one
- Name (R)-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-one
- CAS 70222-88-7
- Purity 99%
Product Details
Buy cost-effective 99% pure (R)-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-one 70222-88-7 now
- Molecular Formula: C10H16 O2
- Molecular Weight: 168.236
- Vapor Pressure: 0.0654mmHg at 25°C
- Boiling Point: 230.6°C at 760 mmHg
- Flash Point: 87.1°C
- PSA： 26.30000
- Density: 1.027g/cm3
- LogP: 1.92310
(R)-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-one(Cas 70222-88-7) Usage
|
General Description |
(R)-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-one is a chemical compound with a unique bicyclic structure. It is a ketone with a melting point of 81-84 degrees Celsius and a boiling point of 105-108 degrees Celsius. (R)-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-one is widely used in the fragrance industry, particularly in the production of perfumes and other scented products. Its pleasant, fruity odor makes it a popular choice for adding a sweet and floral note to fragrances. Additionally, it is also used as a flavoring agent in food products and as a chemical intermediate in the synthesis of other compounds. Due to its versatile applications and pleasing scent, (R)-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-one is commonly utilized in the manufacture of various consumer goods. |
InChI:InChI=1/C10H16O2/c1-9(2)7-4-5-10(3,12-9)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m0/s1
70222-88-7 Relevant articles
Synthesis of oxygenated cineole derivatives from cineole: Utility of cytochrome P450cin as an enantioselective catalyst
Farlow, Anthony J.,Bernhardt, Paul V.,De Voss, James J.
, p. 324 - 333 (2013)
The oxidation of cineole to (1R)-6β-hydr...
Syntheses of chiral 1,8-cineole metabolites and determination of their enantiomeric composition in human urine after ingestion of 1,8-cineole- containing capsules
Schaffarczyk, Monika,Balaban, Teodor Silviu,Rychlik, Michael,Buettner, Andrea
, p. 77 - 85 (2013/06/27)
The chiral metabolites in human urine we...
Cineole biodegradation: Molecular cloning, expression and characterisation of (1R)-6β-hydroxycineole dehydrogenase from Citrobacter braakii
Slessor, Kate E.,Stok, Jeanette E.,Cavaignac, Sonia M.,Hawkes, David B.,Ghasemi, Younes,De Voss, James J.
experimental part, p. 81 - 86 (2010/05/17)
The first steps in the biodegradation of...
70222-88-7 Process route
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![2-endo-hydroxy-1,8-cineole ((1R,6R)-1,3,3-trimethyl-2-oxabicyclo-[2.2.2]octan-6-ol)](/upload/2026/4/79ae3e45afb74bf6a01527643bcd863c_2419c6e4-e8c2-4875-8a3d-71d4253fba97.png)
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18679-48-6,38223-62-0,38223-63-1,54164-88-4,60761-00-4,66965-45-5,92999-78-5,103665-39-0,109009-75-8
2-endo-hydroxy-1,8-cineole ((1R,6R)-1,3,3-trimethyl-2-oxabicyclo-[2.2.2]octan-6-ol)
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18679-55-5,66965-44-4,70222-88-7,107598-08-3
(+/-)-2-oxo-1,8-cineole
| Conditions | Yield |
|---|---|
|
With
Dess-Martin periodane;
In
dichloromethane;
at 20 ℃;
for 24h;
|
70%
|
-
-
98-55-5,2438-12-2
terpineol
-
-
18679-55-5,66965-44-4,70222-88-7,107598-08-3
(+/-)-2-oxo-1,8-cineole
| Conditions | Yield |
|---|---|
|
Multi-step reaction
with
3
steps
1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 0 °C
2: toluene-4-sulfonic acid / dichloromethane / 24 h / 20 °C
3: Dess-Martin periodane / dichloromethane / 24 h / 20 °C
With
Dess-Martin periodane; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
3: |Dess-Martin Oxidation;
|
70222-88-7 Upstream products
-
18679-48-6
(1R)-6β-hydroxycineole
-
98-55-5
terpineol
-
54145-81-2
p-methane-α-1,2-epoxy-8-ol
-
138-86-3
limonene.
70222-88-7 Downstream products
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18679-48-6
(1R)-6β-hydroxycineole
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500698-82-8
6-amino-cyclodecanol
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135420-47-2
1,3,3-trimethyl-6-phenyl-2-oxa-bicyclo[2.2.2]octan-6-ol
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58701-26-1
6-isopropyl-3-methyl-2-oxo-cyclohexanecarboxylic acid methyl ester
